@article {Jung:October 2008:0922-6168:827, author = "Jung, Ji Chul", author = "Lee, Howon", author = "Kim, Heesoo", author = "Chung, Young-Min", author = "Kim, Tae Jin", author = "Lee, Seong Jun", author = "Oh, Seung-Hoon", author = "Kim, Yong Seung", author = "Song, In Kyu", title = "Preparation, characterization and catalytic activity of Bi-Mo-based catalysts for the oxidative dehydrogenation of n-butene to 1,3-butadiene", journal = "Research on Chemical Intermediates", volume = "34", year = "October 2008", abstract = "Multicomponent bismuth molybdates were prepared by a co-precipitation method for use in the oxidative dehydrogenation of n-butene to 1,3-butadiene. The effect of divalent and trivalent metals on the catalytic performance of multicomponent bismuth molybdate catalysts was investigated. It was found that the metal ratio of Fe/Bi/Mo = 3:1:12 was favorable for the reaction. The successful formation of NiXCo8−XFe3Bi1Mo12O50 (X = 0-8) catalysts was well confirmed by XRD and ICP-AES measurements. The multicomponent bismuth molybdate catalysts showed a better catalytic performance than the pure γ-Bi2MoO6 catalyst. Among the NiXCo8-XFe3Bi1Mo12O50 (X = 0-8) catalysts, Ni3Co5Fe3Bi1Mo12O50 showed the highest yield of 1,3-butadiene.", pages = "827-833(7)", url = "http://www.ingentaconnect.com/content/vsp/rci/2008/00000034/F0020008/art00023" doi = "doi:10.1163/156856708786189393" }