@article {Morillo:November 2007:1385-772X:507,
	author = "Morillo, Angel",
	author = "Parada, Alvaro",
	author = "Ibarra, Darmenia",
	author = "Passaglia, Elisa",
	author = "Arevalo, Jose",
	author = "Rajmankina, Tamara",
	title = "Ethylene polymerization using metallocenes supported on MgCl2/SiCl4n (n-C6H13O)n",
	journal = "Designed Monomers & Polymers",
	volume = "10",
	year = "November 2007",
	abstract = "Metallocene complexes Cp<SUB>2</SUB>TiCl<SUB>2</SUB>, Cp<SUB>2</SUB>ZrCl<SUB>2</SUB>, Cp<SUB>2</SUB>Zr(N<SUP><I>n</I></SUP>Bu<SUB>2</SUB>)<SUB>2</SUB>, Cp<SUB>2</SUB>Ti(<I>&#951;</I><SUP>1</SUP>-OC(O)C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>2</SUB> and Cp<SUB>2</SUB>Zr(<I>&#951;</I><SUP>1</SUP>-OC(O)C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>2</SUB> were supported on MgCl<SUB>2</SUB>/SiCl<SUB>4&#8722;<I>n</I></SUB> (<I>n</I>-C<SUB>6</SUB>H<SUB>13</SUB>O)<SUB><I>n</I></SUB> carrier and used for ethylene polymerization. The supported complexes result in highly active catalysts when treated with different aluminum alkyl-based co-catalysts. These catalysts are able of tuning the final properties of the produced polyethylenes. Mixed composites of metallocenes and conventional Ziegler-Natta catalysts supported on the same carrier were also studied. A supported zirconocene Cp<SUB>2</SUB>Zr(<I>&#951;</I><SUP>1</SUP>-OC(O)C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>2</SUB> on MgCl<SUB>2</SUB>/SiCl<SUB>4&#8722;<I>n</I></SUB> (<I>n</I>-C<SUB>6</SUB>H<SUB>13</SUB>O)<SUB><I>n</I></SUB> resulted in a highly active catalyst that eject control on the molecular weight, crystallinity and morphology of the resultant polyethylene.",
	pages = "507-516(10)",
	url = "http://www.ingentaconnect.com/content/vsp/dmp/2007/00000010/00000006/art00003"
	doi = "doi:10.1163/156855507782401187"
}